Materials Analysis Studies on Painting Components and Fossils

MA-XRF

Since its development in 2008, macroscopic X-ray fluorescence scanning (MA-XRF) has allowed to gain insight about the composition and build-up of polychrome works of art by means of elemental distribution maps, obtained in situ through non-destructive analysis. Such scanning instrument provides chemical information from the entire object (both on and below the surface) while the ensuing analytical results are presented in the form of an image

During a MA-XRF experiment, the painting is excited by an X-ray milli-beam to emit X-ray fluorescence radiation. Via the energy of the recorded fluorescence radiation the elements present in the analyzed spot can be identified. By moving the beam relative to the painting, the surface is scanned pixel by pixel. In a next step, the resulting digital data is converted into one or more elemental distribution images by means of software, allowing to study the distribution of various pigments on or beneath the entire paint surface in a visual manner, and this in a non-contact/non-destructive way.

MA-XRF analysis on paintings are usually carried out to support an ongoing conservation treatment with insights into the artist's materials, techniques and degradation mechanisms. Nevertheless, for several master’s such as Van Eyck, Rembrandt or Vermeer the aim is to obtain a significant corpus of data that allows to characterize the studio practice of these artists. The elemental distribution images are also able to reveal and assess the extent of hidden paintings.

Bruker M6 Jetstream preparation for an experiment on Joos Van Cleve's 'Madonna and Child in a Niche'. Collection of the Städel Museum | ©TU Darmstadt.
Bruker M6 Jetstream preparation for an experiment on Joos Van Cleve's 'Madonna and Child in a Niche'. Collection of the Städel Museum | ©TU Darmstadt.
Bruker M6 Jetstream in action on Joos Van Cleve's 'Madonna and Child in a Niche' | ©TU Darmstadt.
Bruker M6 Jetstream in action on Joos Van Cleve's 'Madonna and Child in a Niche' | ©TU Darmstadt.

MA-XRF

Since its development in 2008, macroscopic X-ray fluorescence scanning (MA-XRF) has allowed to gain insight about the composition and build-up of polychrome works of art by means of elemental distribution maps, obtained in situ through non-destructive analysis. Such scanning instrument provides chemical information from the entire object (both on and below the surface) while the ensuing analytical results are presented in the form of an image

During a MA-XRF experiment, the painting is excited by an X-ray milli-beam to emit X-ray fluorescence radiation. Via the energy of the recorded fluorescence radiation the elements present in the analyzed spot can be identified. By moving the beam relative to the painting, the surface is scanned pixel by pixel. In a next step, the resulting digital data is converted into one or more elemental distribution images by means of software, allowing to study the distribution of various pigments on or beneath the entire paint surface in a visual manner, and this in a non-contact/non-destructive way.

MA-XRF analysis on paintings are usually carried out to support an ongoing conservation treatment with insights into the artist's materials, techniques and degradation mechanisms. Nevertheless, for several master’s such as Van Eyck, Rembrandt or Vermeer the aim is to obtain a significant corpus of data that allows to characterize the studio practice of these artists. The elemental distribution images are also able to reveal and assess the extent of hidden paintings.

The MA-XRF portable equipment employed facilitates collaboration with curators, scholars, and private collectors, to assist with questions of process and authenticity, using scientific evidence considered together with connoisseurship, provenance, and art historical research.

The MA-XRF portable equipment employed facilitates collaboration with curators, scholars, and private collectors, to assist with questions of process and authenticity, using scientific evidence considered together with connoisseurship, provenance, and art historical research.

Georg Flegel, Still Life with Fruit and Sweetmeats, c. 1635-37, 19,4 x 23,8 x 0,6 cm, Inv. 2046 | ©Städel Museum.
Georg Flegel, Still Life with Fruit and Sweetmeats, c. 1635-37, 19,4 x 23,8 x 0,6 cm, Inv. 2046 | ©Städel Museum.
Georg Flegel, Still Life with Fruit and Sweetmeats. Pb-L elemental distribution map. The red circles show the compositional changes (pentimenti) | ©TU Darmstadt.
Georg Flegel, Still Life with Fruit and Sweetmeats. Pb-L elemental distribution map. The red circles show the compositional changes (pentimenti) | ©TU Darmstadt.
IMPROVING DATA EXPLORATION METHODS FROM MACRO IMAGING TECHNIQUES: IN SITU SCANNING MACRO-XRF INVESTIGATION ON A MAJOLICA TILE TABLEAU
M. Colombo, S. Legrand, G. V. d. Snickt, K. Janssens
ECR – Studies in Conservation and Restoration 1, 9, 7-25, 2019
DOI: 10.34618/ecr.9.18867
MA-XRF Investigation of the Altenberg Retable from 1330
P. Hoffmann, S. Flege, W. Ensinger, F. Wolf C. Weber, S. Seeberg, J. Sander, J. Schultz, C. Krekel, R. Tagle, A. Wittkopp
X-Ray Spectrometry 47, 215-222, 2018
DOI: 10.1002/xrs.2829
Cover image: DOI: 10.1002/xrs.2844
Die bildgebende Röntgenfluoreszenz-Untersuchung des Altenberger Altars von ca. 1330
F. Wolf, C. Weber, S. Seeberg, J. Sander, P. Hoffmann, S. Flege, W. Ensinger, J. Schultz, C. Krekel
Zeitschrift für Kunsttechnologie und Konservierung 31 (1), 5-33, 2017
Ergebnisse der Röntgenfluoreszenz-Untersuchung des Altenberger Altarschreins
S. Flege, P. Hoffmann, J. Sander, S. Seeberg, C. Weber, F. Wolf, with the co-operation of R. Tagle, L. Drake, W. Ensinger, M. Jost
Supplement of the exhibition catalogue “Schaufenster des Himmels – Heaven on Display”
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