Archaeometry

Micro-XRF

Measuring samples of cultural-historical origin, a measurement technique that is non-destructive and requires no sample preparation is usually obligatory. Depending on the size and materials of the sample a transfer into a vacuum chamber might not be possible. Thus, XRF or a micro-XRF that was developed as a PhD thesis were typically applied. In most cases the results lead to further information, e.g. manufacturing techniques and place of origin or differentiation of genuine or forged pieces.

Archaeometry

Measuring samples of cultural-historical origin, a measurement technique that is non-destructive and requires no sample preparation is usually obligatory. Depending on the size and materials of the sample a transfer into a vacuum chamber might not be possible.

Thus, XRF or a micro-XRF that was developed as a PhD thesis were typically applied.

In most cases the results lead to further information, e.g. manufacturing techniques and place of origin or differentiation of genuine or forged pieces.

Altenberg Altar

In collaboration with the Städel Museum Frankfurt and Bruker Nano the backside of the Altenberg Altar was investigated with a commercial micro-RFA instrument.

The results will be presented in the exhibition “Heaven on display”.

Medieval artefacts

Bichrome glass beads from the Merovingian period

Glass beads are common grave goods found in women's burial places of the Merovingian period. They are of different color (mainly white, orange, green and brown) and are mono- or biochrome with only a few polychrome ones (Millefiori beads). Characterizing the beads scientifically the main and minor components of the glass matrix as well as of the colouring compounds could be determined.

Gold artefacts from a Merovingian grave
Gold artefacts from a Merovingian grave

A find dated between 550 and 575 CE consists of five golden medaillons and two Roman coins fitted with eyes, probably used as ornaments. Comparing the compositions the question could be resolved whether the eyes were there from the outset or were subsequently added.

Ancient coins

Ancient Roman coins consisted of gold or silver, initially in solid form. Plating an ignoble metal a forger could profit accordingly. In later times even the official mints switched over to plating, creating the need for techniques that used less and less noble metals.

BSE image of the cross section of a coin with foil silvering
BSE image of the cross section of a coin with foil silvering

While the first plated Denars used foil silvering with up to 150 µm thickness, the latter ones exhibited only silver containing layers with as small as 1-5 µm thickness. The plating technique and its manufacturing process can be identified by measuring the film thickness, its composition and the one of the core material.

Due to wear and corrosion the original plating can be damaged; a mapping of the silver over the whole surface of the coin with EPMA shows where remnants can be found.

The remaining thickness of the plating can be found out by depth profiling, e.g. with SIMS.

EPMA mapping of the silver on a coin surface
EPMA mapping of the silver on a coin surface

Some Roman Denars show a serrated rim, probably to impede forgeries. However, investigations showed that a later serration of a silvered core was possible.

SE image of a silvery notch of a Denar
SE image of a silvery notch of a Denar
Uncovering Georg Flegel's painting technique by non-invasive state-of-the-art analysis
M. Gerken, M. Colombo, A. Pollmer-Schmidt, C. Weber, B. Thybusch, F. Schütt, P. Hoffmann, W. Ensinger, J. Sander, C. Krekel
Zeitschrift für Kunsttechnologie und Konservierung 2 (2021) 463-479
MA-XRF Investigation of the Altenberg Retable from 1330
P. Hoffmann, S. Flege, W. Ensinger, F. Wolf C. Weber, S. Seeberg, J. Sander, J. Schultz, C. Krekel, R. Tagle, A. Wittkopp
X-Ray Spectrometry 47, 215-222, 2018
DOI: 10.1002/xrs.2829
Die bildgebende Röntgenfluoreszenz-Untersuchung des Altenberger Altars von ca. 1330
F. Wolf, C. Weber, S. Seeberg, J. Sander, P. Hoffmann, S. Flege, W. Ensinger, J. Schultz, C. Krekel
Zeitschrift für Kunsttechnologie und Konservierung 31 (1), 5-33, 2017
Characterization of mortars and plasters of Palatium and Einhard Basilica in Seligenstadt, Germany
A.Cwirzen, K.M.E. Habermehl-Cwirzen, S. Flege, A.G. Balogh
in Proc. of 1st Historical Mortars Conference, Lisbon, September 2008
Characterization of mortars from the historic iron work in Teijo, Finland – a case study
K. Habermehl-Cwirzen, A.Cwirzen, S. Flege, A.G. Balogh
in Proc. of 1st Historical Mortars Conference, Lisbon, September 2008
Analysis of the notches of ancient serrated denars
G. Kraft, S. Flege, F. Reiff, H.M. Ortner, W. Ensinger
Archaeometry, 48, 605-612, 2006
EPMA Investigation of Roman Coin Silvering Techniques
G. Kraft, S. Flege, F. Reiff, H.M. Ortner, W. Ensinger
Microchimica Acta, 155, 179-182, 2006
Investigation of contemporary forgeries of ancient silver coins
G. Kraft, S. Flege, F. Reiff, H.M. Ortner
Mikrochim. Acta, 145, 87-90, 2004
On the Use of Mössbauer Spectroscopy for the Quantification of Fe (II)/Fe (III) in Ancient Manuscripts
E. Bulska, B. Wagner, B. Stahl, M. Heck, H. M. Ortner
Extended abstract, Proceedings of: “art 2002”, 7th Intern. Conference on Non-Destructive Testing and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, Antwerp, June 2 – 6 (2002)
Comparative material characterization of historical and industrial samples by using a compact micro-XRF spectrometer
S. Bichlmeier, K. Janssens, J. Heckel, P. Hoffmann, H.M. Ortner
X-Ray Spectrometry 31, 87-91, 2002
Analysis of Early Medieval Glass Beads – The Raw Materials to Produce Green, Orange and Brown Colours
M. Heck, P. Hoffmann
Mikrochim. Acta 139, 71-76, 2002